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Fixatives and Their Function in Natural Perfumery
Written By: Eden Botanicals
At Eden Botanicals, we receive many inquiries about fixatives, so we decided to dedicate an article on the topic. Although this is a more advanced Natural Perfumery subject, we want our customers who are just starting out to have a better understanding of what fixatives actually are and how they function in perfume compositions.
What is a fixative and what is its purpose in Natural Perfumery?
Fixatives are materials that:
1. Slow down the rate of evaporation of the more volatile materials in a perfume composition, causing only gradual changes in the aroma of the perfume as the ingredients in it fade away;
2. Lend a particular note to the perfume throughout all stages of evaporation but do not significantly affect the vaporation rate of the other materials in the perfume;
3. Improve, fortify, and/or transport the vapors and/or lend a combination of a diffusive or retentive effect, typically through the addition of trace amounts;
4. And/or are odorless or almost odorless and lend a stabilizing action by paralyzing the odor of the low-boiling (volatile) materials in the perfume.[1,2]
Remember that the fixative qualities of an oil and an oil’s tenacity do not necessarily mean the same thing. Tenacity is the lasting effect of a perfume material and its ability to linger on the skin. An aromatic perfume ingredient may have immense tenacity but may have little impact on the evaporation rate of the other perfume ingredients it’s combined with (i.e., be able to impart fixative qualities). Examples are Davana, Helichrysum, and Tuberose.
Why should one learn the benefits of incorporating fixatives into Natural Perfumery?
Natural perfumes are a blessing for those of us who choose to steer away from mainstream fragrances that have very little resemblance to perfumes of times past when nearly all ingredients were obtained from botanical and animal sources. But because of the ephemeral quality and volatile nature of botanical perfume ingredients, it is crucial to become familiar with and know the value of incorporating fixatives into perfume compositions to impart longevity. This is especially important due to the fact that animal fixatives (ex: Ambergris, Civet), highly prized in past formulations, are costly, rare or unavailable, may be illegally or unethically obtained, and have been almost entirely replaced with much cheaper, manufactured materials.
Understanding the limits of fixatives and the true nature of Natural/Botanical Perfumes:
The fact that natural perfumes differ from synthetic perfumes in their longevity and their sillage – the degree to which a perfume’s fragrance lingers and/or disperses in the air when worn – can be a disappointment and a determining factor to those new to perfumes made with botanical aromatic materials. While a botanical fixative will impart longevity and help extend the sillage of a natural perfume, in most cases it will not be as effective as a synthetic fixative. Maybe this difference is actually a good thing.
Perhaps what some consider as the ever-increasing aromatic assault of synthetic perfume ingredients on our collective noses has over time brought out a natural defense, or a numbing down of the nose as it becomes “used” to these new, manmade scent molecules such that primal, made-in-nature materials no longer appeal or seem weak or uninteresting. Natural/botanical perfumes offer an olfactory reprieve and, to many, the return to healthier, holistic aromatic pleasures wherein the importance of longevity and sillage is not so paramount as is a renewed and much needed appreciation of and reconnection with the beautiful intelligence of our natural world.
Some Common Fixatives:
For a full listing of oils with Fixative properties carried by Eden Botanicals, please visit the Natural Perfumery Basics section of our website.
Ambrette: Known for its exalting (lifting) effect, has an incredibly tenacious rich, sweet floral-musky distinctly wine- or brandy-like odor (used as a musk substitute); blends well with rose, neroli, sandalwood, clary sage, cypress, patchouli, amber and ‘sophisticated’ bases. Use very sparingly.Amyris: Has a very tenacious, rich, complex odor that quickly fades out to a weak woody-balsamic scent, but is still a well-known fixative; it finds extensive application as a mild blender in numerous types of perfumes and blends well with lavandin, oakmoss, citronella, rose, Virginia cedarwood, etc.Angelica: Unique tenacity and great diffusive power, base note – use very sparingly; blends well with patchouli, oakmoss, clary sage, vetiver, and special citrus blends.Balsam of Peru: Has a rich, sweet, balsamic vanilla-like odor; blends well with ylang-ylang, patchouli, petitgrain, sandalwood, spice oils, floral oils, most citrus oils, and amber bases. An excellent fixative for rose, heliotrope, magnolia, and lilac perfumes.Cedarwood (Atlas): Has a sweet tenacious, woody-balsamic odor with a warm camphor-like top note; blends well with bergamot, cypress, cassie, clary sage, frankincense, jasmine, juniper, labdanum, lavandin, neroli, rose, rosemary, vetiver, ylang-ylang, amber and floral bases.Cistus / Labdanum: Has a rich, sweet, herbal-balsamic, slightly leathery fragrance, and a characteristic ambergris-like odor. Extremely tenacious and a fixative par excellence, it blends well with oakmoss, clary sage, juniper, lavender, lavandin, bergamot, cypress, vetiver, sandalwood, patchouli, frankincense (olibanum), and amber bases.Clary Sage: Has an herbal-sweet, nut-like fragrance with unusual tenacity; somewhat heavy with a balsamic, ambergris-like dryout reminiscent of tobacco, sweet hay, and tea leaves. An excellent fixative that can be used with perfumes of a more delicate bouquet, and with bergamot, cedarwood, citronella, cognac, cypress, geranium, frankincense, grapefruit, jasmine, juniper, labdanum, lavender, lime, and sandalwood.Frankincense: Has a fresh warm, rich, sweet-balsamic, spicy odor with a hint of turpentine-like top note, used with very heavy fragrances; blends well with basil, black pepper, bergamot, galbanum, geranium, grapefruit, lavender, orange, melissa, neroli, patchouli, vetiver, sandalwood, and other spice oils. It modifies the sweetness of citrus blends in an intriguing way.Galbanum: Has a remarkably powerful fresh extremely dry/tart green leaf odor with a woody-dry balsamic or damp woods undertone. A modifier that blends well with lavender, oakmoss, fir, Liquidambar (styrax), elemi, jasmine, frankincense, palmarosa, geranium, ginger, rose, verbena, ylang-ylang, and amber bases (use very, very sparingly).Liquidambar (Styrax): Has a very rich, sweet-balsamic, faintly floral, somewhat spicy aroma, with a peculiar styrene topnote and resinous, animalic, amber-like undertones; to be used most sparingly and has excellent fixative qualities. An important element in lilac, narcissus, jonquil, hyacinth, jasmine, tuberose, and wisteria bases; it also blends well with ylang-ylang, rose, lavender, carnation, violet, cassie and spice oils. Benign solvent (ethanol) extracted Resinoid.Myrrh: An excellent fixative with a smoky-woody or warm sweet-balsamic and slightly spicy-medicinal odor, and is excellent with violet, white rose, and lavender; also blends well with frankincense, sandalwood, oakmoss, cypress, juniper, mandarin, geranium, patchouli, thyme, mints, and spice oils, and in heavy floral blends.Oakmoss: Has a heavy, rich earthy-mossy, bark-like and extremely tenacious fragrance with a high fixative value; blends well with virtually all other oils, including lavender and ylang-ylang. Used to lend body and rich natural undertones to all perfume types.Orris: Has a delicate sweet floral-woody odor; blends well with carnation, cassie, cedarwood, bergamot, vetiver, cypress, geranium, mimosa, labdanum, clary sage, rose, violet, and other florals.Patchouli: Displays outstanding richness and tenacity, with a strong rich earthy-herbal and pungent odor ; can be used in amber bouquets, and with bergamot, black pepper, cassie, cedarwood, cinnamon, clary sage, clove, elemi, frankincense, galbanum, geranium, ginger, jasmine, labdanum, lavender, lemongrass, myrrh, neroli, oakmoss, orris, rose, rosewood, sandalwood, and vetiver.Sandalwood: Has a deep, soft, sweet-woody balsamic fragrance with excellent tenacity; blends well with violet note perfumes, bergamot, black pepper, cassie, clove, geranium, jasmine, labdanum, lavender, myrrh, oakmoss, patchouli, rose, rosewood, tuberose, and vetiver.Vanilla: Has quite an outstanding tenacity and a sweet, balsamic odor that lends an unsurpassed richness and depth to many types of sweet-floral or heavy amber bases, etc., where it blends excellently with sandalwood, vetiver, balsams, and spice oils, also cassie, lavandin and lavender.Vetiver: Deep, smoky and earthy-woody fragrance with a sweet persistent undertone; can be used in amber bouquets, and with frankincense, patchouli, oakmoss, sandalwood, violet, ylang-ylang, galbanum, geranium, jasmine, lavender, clary sage, cassie, and rose.Violet Leaf: Has a dry, strong, fresh green-leaf odor with a hay-like or delicate floral undertone; has tremendous diffusion and delicate naturalness when used in very low concentrations. Lends an unsurpassed elegance in certain floral blends, e.g., hyacinth, muguet, high-class chypres, etc. Blends excellently with sandalwood, frankincense, lavender, rose, jasmine, tuberose, clary sage, cumin, basil, and most citrus oils.
Sources:
Arctander, Steffen. Perfume and Flavor Materials of Natural Origin (originally self-published in 1960).Groom, Nigel. The New Perfume Handbook, 2nd Edition, Chapman Hall, London, UK, 1997.Lawless, Julia. The Illustrated Encyclopedia of Essential Oils, Element Books, Dorset, UK, 1995.
Footnotes:
1 Arctander, Steffen. Perfume and Flavor Materials of Natural Origin, 1960, pp. 18-9.
2 Groom, Nigel. The Perfume Handbook, 2nd ed., 1997, p. 123.